Countries starting with A I
| Country (memorize) | Capital (memorize) |
| Abkhazia* | Sukhumi |
| Afghanistan | Kabul |
| Akrotiri and Dhekelia | Episkopi Cantonment |
| Aland | Mariehamn |
| Albania | Tirana |
| Algeria | Algiers |
| American Samoa | Pago Pago |
Countries starting with A II
| Question (memorize) | Answer (memorize) |
| Andorra | Andorra la Vella |
| Angola | Luanda |
| Anguilla | The Valley |
| Antigua and Barbuda | Saint John's |
| Argentina | Buenos Aires |
| Armenia | Yerevan |
| Aruba | Oranjestad |
Countries starting with A III
| Question (memorize) | Answer (memorize) |
| Ascension Island | Georgetown |
| Australia | Canberra |
| Austria | Vienna |
| Azerbijan | Baku |
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